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Category:Horror film actressesA Highly Efficient Enantioselective Wacker Process: Conversion of α- and β-Oximes into the Corresponding Azaheterocycles.
The first Wacker-type domino reaction between α- and β-oximes and nitro-arenes is described. The oxime is efficiently generated from aryl oximes in a five-step sequence. The resultant oximes were transformed into oxazoles and benzoxazepines in good to excellent yields with excellent to excellent enantioselectivities. The reaction was sensitive to water; the corresponding oxazoles could be easily prepared in high yield and enantiomeric excess (ee) from stable hydrated oximes, and benzoxazepines could be obtained from less reactive nitro-arenes.S ac619d1d87
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